Defending champions, Real Madrid will have a seemingly easy contest against Eredivisie side, Ajax Amsterdam.
Lyon coach Bruno Genesio says his team can draw on their group-stage displays against City - a 2-1 away win and 2-2 home draw - ahead of their clash with five-time European champions Barca.
It will be a 50/50 chance when Mauricio Pochettino's side, Tottenham play against surprise Group A winners, Borussia Dortmund.
Around the same time, United have a daunting face-off with Ligue 1 champions Paris Saint-Germain, with some fans positively cringing at the prospect of a defence likely to include Phil Jones and Chris Smalling having to stand up to Edinson Cavani, Neymar, and Kylian Mbappe.
The first leg will be at home on Wednesday 13 February.
Of course, Klopp's background means he is well acquainted with Bayern and he offered his thoughts on the tie to Liverpoolfc.com immediately after the draw.
Spanish football pundit and former Real Madrid player and manager Jorge Valdano said: 'Juventus are not happy either.
Olmpique Lyonnais will square up against Spanish champions FC Barcelona.
It is, though, the first time the Red Devils will have played the French side, who are unbeaten in their own domestic division this season with some 44 points from 16 league games.
Liverpool are now fifth favourites to go one step further than past year - when they reached the Final in Kiev to be ultimately defeated by Real Madrid - and go on to lift the most prestigious trophy in club football for the sixth time.
The Europe elite competition has now got to its interesting stage as no team will have the luxury of depending on other results to qualify. It will be an historic tie between two teams who have helped make the competition what it is'. Schalke is in 13th place in the Bundesliga.
The prime minister won the confidence vote with a majority of 83 - 63% of Conservative MPs backing her and 37% voting against her. The vote had been triggered by MPs angry at her Brexit policy, which they say betrays the 2016 referendum result.
The Celtics scored nine straight points in the last four minutes of the first quarter to take a lead they would never relinquish. The Celtics may need you to come off the bench, because they have about three healthy players for Monday night's game.
Perhaps trying to emulate that game a little, Counter-Strike: GO now has a Battle Royale mode ...and has also gone free-to-play. In addition, the game is now completely free to play, following the previous September announcement of a separate Free Edition .
But the German, who has lost three finals during his time at the club, said there was more to consider than just trophies. Asked how far away United are from being a team in their manager's image, Mourinho said: "Far".
She is also exploring whether some of those provisions could also be implemented in the House rules for the next Congress . Tim Walz , Minnesota's Democratic governor-elect and member of the House Agriculture Committee, did not vote, nor did U.S.
For optimal viewing conditions, the sky must be clear, get as far away from city lights as possible, and face south. Light from the moon makes it harder to see some fainter meteors, so it's best to wait until it sets to head outside.
Mr Trump and Schumer jabbed at each other over the import of the midterm elections - and who will be blamed if a shutdown occurs. Interested in Democratic Party? Pelosi and Schumer both implored Trump not to shutdown the government.
Quarterback Angelo Bertelli was the first Heisman victor for the Fighting Irish and won the the trophy in 1943. Oklahoma's Baker Mayfield won the Davey O'Brien and Maxwell awards on his way to the 2017 Heisman Trophy.
It should never have come to this for Klopp's side, but consecutive defeats to Red Star Belgrade and PSG mean that it has. The best form of defence is a good offence... unless you're playing Liverpool . "I'm really looking forward to it".
Beijing has said that the Hong Kong-based organization for which Kovrig now works was not properly registered in China. Meng is a high-profile executive at Huawei, one of the world's biggest makers of smartphones and networking equipment.
Bollywood singer Mika Singh has been detained in Dubai after a Brazilian girl complained that he sent her obscene messages. Mika had recently travelled to the Arab nation to perform at a Bollywood event, which was reportedly the Masala Awards.
Koscielny set for first Arsenal start since May
Arsenal manager Unai Emery has conceded he may look into attaining a new defensive option in the January transfer window, with the centre of his defence suffering from a lack of depth and fitness.
Theresa May says she won't run in next general election
Many Conservative politicians do not want May to lead the party into that vote, given her poor performance in the UK's 2017 poll. One of her cabinet colleagues is predicting a "long day" but a "solid win". "I will contest that vote with everything I've got".
Rajasthan, Madhya Pradesh, Telangana, Chhattisgarh, Mizoram
In the 2013 elections, the BJP won 49 seats, the Congress 39, while one seat each was bagged by the BSP and an Independent. As many as 5,184 counting personnel and 1,500 micro-observers have been appointed for smooth conduct of the process.
James Fields found guilty of killing of Heather Heyer
In another, Fields referred to the mother of the woman who was killed as a "communist" and "one of those anti-white supremacists". During the trial, prosecutors introduced evidence that Fields meant to commit harm when he drove from OH to attend the rally.
Marlboro owner Altria makes £1.4bn bet on cannabis
Altria will make Cronos its exclusive partner for all world-wide cannabis-related investments, with some limited exceptions. Michelle Wine Estates and Marlboro, has announced a $1.8 billion investment in Canadian cannabis company Cronos Group.